Thermal Degradation Behavior of Liquid Crystalline Thermoset Composites
نویسندگان
چکیده
Liquid crystalline thermosetting epoxy, 4,4'-diglycidyloxy-α-methylstilbene (DOMS) was synthesized and characterized with cross-polarized optical microscopy (POM) and differential scanning calorimetry (DSC). Carbon nanotube (CNT) or graphene reinforced DOMS composites were fabricated by melt blending with sulfanilamide (SAA) as a curing agent. To investigate the thermal degradation behavior, thermogravimetric analysis (TGA) was performed under nitrogen atmosphere in the temperature range from 30 to 1000 oC. Activation energies for decomposition (Ed) were determined by TGA as a function of the conversion by weight loss processes.
منابع مشابه
Evaluation of Thermal and Thermomechanical Behaviour of Bio-Based Polyamide 11 Based Composites Reinforced with Lignocellulosic Fibres
In this work, polyamide 11 (PA11) and stone ground wood fibres (SGW) were used, as an alternative to non-bio-based polymer matrices and reinforcements, to obtain short fibre reinforced composites. The impact of the reinforcement on the thermal degradation, thermal transitions and microstructure of PA11-based composites were studied. Natural fibres have lower degradation temperatures than PA11, ...
متن کاملبررسی سینتیک تخریب حرارتی پیشرانه جامد کامپوزیتی HPG
In this work, thermal degradation behavior of a solid composite propellant containing Epoxy/Ammonium perchlorateStrontium nitrateAnthracene composite was studied by simultaneous thrmogravimetric analysis and differential scanning calorimetry under dynamic nitrogen atmosphere at different heating rates. Variation curves of the thermal degradation activation energy of EpoxyAmmonium perchlorateStr...
متن کاملAn investigation on injectable composites fabricated by 45S5 bioactive glass and gum tragacanth: Rheological properties and in vitro behavior
The injectable composites were formulated from melt-derived 45S5 bioactive glass powder and gum tragacanth. The effect of tragacanth concentration (2 and 4 w/v%) and powder to liquid ratio (P/L= 1.5 to 2.5) on rheological properties, injectability, degradation, swelling, and bioactivity the composites was studied. With the increase of P/L ratio and tragacanth concentration, the force requ...
متن کاملSurface Degradation of Polymer Matrix Composites Under Different Low Thermal Cycling Conditions
The principal effects of mass degradation on polymer matrix composites (PMCs) are the decay of mechanical properties such as strength, elongation, and resilience. This degradation is a common problem of the PMCs under thermal cycling conditions. In this article, composite degradation was investigated by measurement of total mass loss (TML) using the Taguchi approach. Thermal cycling tests were ...
متن کاملOpen-Hole Size and Thermal Cycling Effects on Mass Loss and Surface Degradation of Polymer Matrix Composites
Degradation is a common problem for polymer matrix composites (PMCs) under low thermal cycling conditions. This paper investigates the effects of low thermal cycling on total mass loss (TML) and surface degradation of PMCs. Unnotched and open-hole specimens were weighed before and after low thermal cycling. The total mass loss and surface degradation of the specimens were studied over 250 cycle...
متن کامل